Syllabus ( CED 626 )
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Basic information
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Course title: |
Polymerization Kinetics and Reactor Design |
Course code: |
CED 626 |
Lecturer: |
Assist. Prof. Çiğdem TAŞDELEN-YÜCEDAĞ
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ECTS credits: |
7.5 |
GTU credits: |
3 (3+0+0) |
Year, Semester: |
2018-2019, Fall and Spring |
Level of course: |
Third Cycle (Doctoral) |
Type of course: |
Area Elective
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Language of instruction: |
English
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Mode of delivery: |
Face to face
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Pre- and co-requisites: |
none |
Professional practice: |
No |
Purpose of the course: |
This course covers polymerization reaction kinetics and reactor design. Polymerization reactions, step growth, chain growth and controlled/living polymerization mechanisms, mathematical modeling, design and control of polymerization reactors are discussed within the context of this course. |
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Learning outcomes
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Upon successful completion of this course, students will be able to:
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Explain the mechanisms and kinetics of polymerization reactions.
Contribution to Program Outcomes
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Define and manipulate advanced concepts of Chemical Engineering in a specialized way
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
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Summarize, document, report and reflect on progress
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Acquire scientific knowledge and work independently,
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Find out new methods to improve his/her knowledge.
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Analyze the polymers by using NMR, GPC/SEC techniques and spectroscopic methods.
Contribution to Program Outcomes
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Define and manipulate advanced concepts of Chemical Engineering in a specialized way
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Pick out and validate problems relevant to his/her field,
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
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Work effectively in multi-disciplinary research teams
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Support his/her ideas with various arguments and present them clearly to a range of audience, formally and informally through a variety of techniques
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Choose appropriate methods for the monitoring of polymerization reactors.
Contribution to Program Outcomes
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Pick out and validate problems relevant to his/her field,
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
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Summarize, document, report and reflect on progress
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Acquire scientific knowledge and work independently,
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Support his/her ideas with various arguments and present them clearly to a range of audience, formally and informally through a variety of techniques
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Analyze a process and develop a mathematical model.
Contribution to Program Outcomes
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Pick out and validate problems relevant to his/her field,
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Gain original, independent and critical thinking, and develop theoretical concepts and tools,
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
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Summarize, document, report and reflect on progress
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Question and find out innovative approaches.
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Design a controlled reactor for a specific process by considering the kinetic mechanisms and characterization methods.
Contribution to Program Outcomes
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Pick out and validate problems relevant to his/her field,
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Gain original, independent and critical thinking, and develop theoretical concepts and tools,
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
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Summarize, document, report and reflect on progress
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Question and find out innovative approaches.
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Work as a team member in the same discipline for a project.
Contribution to Program Outcomes
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Gain original, independent and critical thinking, and develop theoretical concepts and tools,
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Understand relevant research methodologies and techniques and their appropriate application within his/her research field
-
Summarize, document, report and reflect on progress
-
Work effectively in multi-disciplinary research teams
-
Support his/her ideas with various arguments and present them clearly to a range of audience, formally and informally through a variety of techniques
Method of assessment
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Written exam
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Homework assignment
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Seminar/presentation
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Term paper
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Contents
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Week 1: |
Introduction to polymerization reactions. |
Week 2: |
Polymerization reactions and kinetics: free radical polymerization. |
Week 3: |
Polymerization reactions and kinetics: free radical polymerization (cont.), condensation polymerization. |
Week 4: |
Polymerization reactions and kinetics: condensation polymerization (cont.). |
Week 5: |
Controlled/living polymerization methods of vinyl monomers: living anionic, living cationic and coordination-insertion. |
Week 6: |
Controlled/living polymerization methods of vinyl monomers: controlled radical polymerization. |
Week 7: |
Polymerization characterization and monitoring methods: polymer characteristics and spectroscopic methods. |
Week 8: |
Midterm |
Week 9: |
Polymerization characterization and monitoring methods: calorimetry, conductivity, densimetry and rheological measurements. |
Week 10: |
Determination of macromolecular properties by GPC/SEC method. |
Week 11: |
Automatic continuous online monitoring of polymerization reactions (ACOMP). |
Week 12: |
Mathematical modeling of polymerization reactors. |
Week 13: |
Design and control of polymerization reactors. |
Week 14: |
Project presentations. |
Week 15*: |
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Week 16*: |
Final. |
Textbooks and materials: |
W. F. Reed, & A. M. Alb. (2014). Monitoring Polymerization Reactions: From Fundamentals to Applications, New York: John Wiley & Sons. ISBN: 978-0-470-91738-1. |
Recommended readings: |
T. Meyer & J. Keurentjes (2005). Handbook of Polymer Reaction Engineering, Weinheim: John Wiley & Sons. ISBN: 978-3-527-31014-2. C. McGreavy. (1994). Polymer Reactor Engineering, 1st edition, Springer. ISBN: 978-94-010-4583-4. G. Odian. (2004). Principles of Polymerization, 4th Edition, New York: John Wiley & Sons. ISBN: 0-471-27400
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* Between 15th and 16th weeks is there a free week for students to prepare for final exam.
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Assessment
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Method of assessment |
Week number |
Weight (%) |
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Mid-terms: |
8 |
30 |
Other in-term studies: |
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0 |
Project: |
14 |
15 |
Homework: |
3-13 |
15 |
Quiz: |
- |
0 |
Final exam: |
16 |
40 |
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Total weight: |
(%) |
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Workload
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Activity |
Duration (Hours per week) |
Total number of weeks |
Total hours in term |
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Courses (Face-to-face teaching): |
3 |
14 |
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Own studies outside class: |
3 |
14 |
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Practice, Recitation: |
0 |
0 |
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Homework: |
8 |
5 |
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Term project: |
8 |
5 |
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Term project presentation: |
1 |
1 |
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Quiz: |
0 |
0 |
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Own study for mid-term exam: |
10 |
1 |
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Mid-term: |
3 |
1 |
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Personal studies for final exam: |
10 |
1 |
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Final exam: |
3 |
1 |
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Total workload: |
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Total ECTS credits: |
* |
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* ECTS credit is calculated by dividing total workload by 25. (1 ECTS = 25 work hours)
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